| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. George Kahema Madafa | Ambassador | 2017 - 2021 |
| 2 | H.E. Dr. James Alex Msekela | Ambassador | 2012 - 2017 |
| 3 | H.E. Ali Abeid Amani Karume | Ambassador | 2006 - 2011 |
| 4 | H.E Prof. Costa Ricky Mahalu | Ambassador | 2000 - 2006 |
| 5 | H.E. Daudi N. Mwakawago | Ambassador | 1992 - 1994 |
| 6 | H.E. Abbas K. Sykes | Ambassador | 1982 - 1989 |
| 7 | H.E. George Samweli Magombe | Ambassador | 1980 - 1982 |
| 8 | H.E. Mohamed A. Foum | Ambassador | 1977 - 1978 |
| 9 | H.E. Raphael Lukindo | Ambassador | 1972 - 1976 |
